Simple. economic and sensitive mathematical spectrophotometric methods were developed for the estimation 4-aminoantipyrine in presence of its acidic product. The estimation of binary mixture 4-aminoantipyrine and its acidic product was achieved by first derivative and second derivative spectrophotometric methods by applying zero-crossing at (valley 255. 9nm and 234. https://www.nacrack.com/flash-deal-Diamond-Painting-Zee-en-strand-special-find/